| 二茂铁基苯酰腙的d区金属螯合物的合成和表征 |
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| 引用本文： | 方新钦,张伦,张铁灵.二茂铁基苯酰腙的d区金属螯合物的合成和表征[J].无机化学学报,1988,4(3):20-27. |
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| 作者姓名： | 方新钦 张伦 张铁灵 |
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| 作者单位： | 武汉大学化学系，武汉大学化学系，武汉大学化学系 1986届毕业生，中科院华南植物所 |
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| 摘 要： | 二茂铁基苯酰腙与d区金属乙酸盐或氯化物在乙醇中反应,得到了6个新的螯合物,分子式为M(Fcbh)nFcbh=Fc—C=N—N=C-C_6H_5,Fc=C_5H_5—FeC_5H_4;M=Cr(Ⅲ)、Fe(Ⅲ)时,n=3;M=Mn(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)时,n=2]和Pd(Fcbh—H)_2Cl_2Fcbh—H=Fc—C=N—NHCOC_6H_5]通过元素分析,红外光谱,H核磁共振谱和质谱,确定了螯合物的组成和结构。描述了二茂铁基苯酰腙配体与d区金属的两种不同的配位方式。
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| 关 键 词： | 二茂铁基苯酰腙 d区金属螯合物 配位方式 |
| 收稿时间： | 1987/4/28 0:00:00 |
SYNTHESIS AND CHARACTERIZATION FOR d-BLOCK METAL CHELATES OF FER-ROCENYL BENZOYL HYDRAZONE |
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| Fang Xinqin,Zhang Lun and Zhang Tielin.SYNTHESIS AND CHARACTERIZATION FOR d-BLOCK METAL CHELATES OF FER-ROCENYL BENZOYL HYDRAZONE[J].Chinese Journal of Inorganic Chemistry,1988,4(3):20-27. |
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| Authors: | Fang Xinqin Zhang Lun and Zhang Tielin |
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| Institution: | Department of Chemistry, Wuhan University,Department of Chemistry, Wuhan University and Department of Chemistry, Wuhan University |
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| Abstract: | Six new chelates were synthesized via the reactions of transition metal acetates or chlorides with ferrocenyl benzoyl hydrazone. These chelates have been characterized by elemental analyses, IR, 1HNMR and mass spectra. Two different patterns in which the ligand C5H5FeC8H4-C=N-
NH-C-C6H5 coordinates with d-block metals were described. |
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| Keywords: | ferrocenyl benzoyl hydrazone d-block metal chelates coordinate patterns |
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