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Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials
引用本文:Hao Chen Xing Xu He Gang Yan Xian Rong Cai Ying Li Qing Jiang Ming Gui Xie. Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials[J]. 中国化学快报, 2007, 18(12): 1496-1500. DOI: 10.1016/j.cclet.2007.10.005
作者姓名:Hao Chen Xing Xu He Gang Yan Xian Rong Cai Ying Li Qing Jiang Ming Gui Xie
作者单位:Hao Chen Xing Xu He Gang Yan Xian Rong Cai Ying Li Qing Jiang Ming Gui Xie College of Chemistry,Sichuan University,Chengdu 610064,China
基金项目:教育部科学基金重点项目
摘    要:A series of novel fluorene-carbazole-based copolymers with pyrazoline and benzothiazole units were synthesized successfully through Suzuki coupling reactions.The molecular structures and thermal properties of these polymers were characterized by FT-IR, ~1H NMR,DSC and TGA.GPC results indicated that the weight-average molecular weight(M_w) and polydispersity of these polymers were in range(12,000-14,000)and(1.8-2.0),respectively.The two resulting polymers have high photoluminescence quantum efficiency implying that they may be promising candidates for polymer light-emitting diodes (PLEDs).

关 键 词:芴-咔唑 共聚物 二氢化吡唑 化学分析
收稿时间:26 June 2007. 

Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials
Hao Chen, Xing Xu, He Gang Yan, Xian Rong Cai, Ying Li, Qing Jiang,Ming Gui Xie. Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials[J]. Chinese Chemical Letters, 2007, 18(12): 1496-1500. DOI: 10.1016/j.cclet.2007.10.005
Authors:Hao Chen   Xing Xu   He Gang Yan   Xian Rong Cai   Ying Li   Qing Jiang  Ming Gui Xie
Affiliation:

aCollege of Chemistry, Sichuan University, Chengdu 610064, China

Abstract:A series of novel fluorene-carbazole-based copolymers with pyrazoline and benzothiazole units were synthesized successfully through Suzuki coupling reactions.The molecular structures and thermal properties of these polymers were characterized by FT-IR, ~1H NMR,DSC and TGA.GPC results indicated that the weight-average molecular weight(M_w) and polydispersity of these polymers were in range(12,000-14,000)and(1.8-2.0),respectively.The two resulting polymers have high photoluminescence quantum efficiency implying that they may be promising candidates for polymer light-emitting diodes (PLEDs).
Keywords:Fluorene-carbazole copolymers  Pyrazoline  Bezothiazole
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