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Vibronic intensity borrowing. Deuterium effect and emission—absorption asymmetry of the S1---S0 transition in pyrene |
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| Authors: | K. Cunningham W. Siebrand Digby F. Williams G. Orlandi |
| Affiliation: | Division of Chemistry, National Research Council of Canada, Ottawa, Canada, K1A 0R6 Laboratorio di Fotochimica e Radiazione d'Alta Energia del CNR, 40126 Bologna, Italy |
| Abstract: | The intensities of the vibrationally induced bands in the S1---S0 emission and absorption spectra of pyrene-h10 and -d10 are measured and analysed. Several new expressions are reported which relate the deuterium effect and emission—absorption asymmetry of induced spectra to the vibronic coupling mechanism. |
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