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掺杂改性纳米TiO2降解挥发性污染物及产物研究
引用本文:赵鹏,刘杰民,范慧俐,韦祎,何荣亮,曹文斌. 掺杂改性纳米TiO2降解挥发性污染物及产物研究[J]. 影像科学与光化学, 2009, 27(5): 367-372. DOI: 10.7517/j.issn.1674-0475.2009.05.367
作者姓名:赵鹏  刘杰民  范慧俐  韦祎  何荣亮  曹文斌
作者单位:北京科技大学,应用科学学院,北京,100083;北京科技大学,材料科学学院,北京,100083
摘    要:本文系统研究了水热法制备的铁掺杂纳米TiO2和氮掺杂纳米TiO2在可见光照射下对挥发性有机物(volatile organic compounds,VOCs)的降解能力和降解产物.铁掺杂纳米TiO2和氮掺杂TiO2对光的吸收边分别红移到540 nm和580 nm;在可见光下具有良好的催化活性,24 h内对挥发性有机物的降解率达20%—50%,降解后的最终产物可能主要为CO2.

关 键 词:掺杂纳米TiO2  可见光  降解效率  挥发性有机物
收稿时间:2009-04-15

The Degradation Efficiency and Degradation Products of Volatile Organic Compounds Using Doped-TiO2 Photocatalyst
ZHAO Peng,LIU Jie-min,FAN Hui-li,WEI Yi,HE Rong-liang,CAO Wen-bin. The Degradation Efficiency and Degradation Products of Volatile Organic Compounds Using Doped-TiO2 Photocatalyst[J]. Imaging Science and Photochemistry, 2009, 27(5): 367-372. DOI: 10.7517/j.issn.1674-0475.2009.05.367
Authors:ZHAO Peng  LIU Jie-min  FAN Hui-li  WEI Yi  HE Rong-liang  CAO Wen-bin
Affiliation:1. School of Applied Science, University of Science and Technology Beijing, Beijing 100083, P.R.China;2. School of Materials Science and Engineering, University of Science andTechnology Beijing, Beijing 100083, P.R.China
Abstract:The degradation performance of volatile organic compounds(VOCs) under visible light irradiation by Fe-doped and nitrogen-doped nanocrystalline TiO2 powders prepared by hydrothermal method has been investigated systematically in this article.The absorption spectral edge of Fe-doped and N-doped nano-TiO2 powders have been red-shifted to nearly 540 nm and 580 nm,respectively.Experimental results show that the degradation ratio of VOCs was over 20% to 50% within 24 hours.CO2 was one of the final degradation products.
Keywords:doped nano-TiO2  visible light  degradation ratio  volatile organic compounds
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