TiOBr; Darstellung,Eigenschaften und Struktur* |
| |
Authors: | Hans Georg V. Schnering Marianne Collin Margret Hassheider |
| |
Abstract: | TiOBr was prepared by reaction of Ti with TiO2 and Br2. The compound forms fiat reddish-brown needles and shows a temperature independent weak paramagnetism. It crystallises in the orthorhombic system (Pmmn; a = 3.787, b = 3.487, c = 8.529 Å) with the FeOCl type of structure. The interatomic distances are Ti?O = 1.952; 2.245 Å (2X) and Ti?Br = 2.544 Å (2X). |
| |
Keywords: | |
|
|