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表面改性医用橡胶的光谱研究
引用本文:罗传秋,刘泳,杨继萍,翁健. 表面改性医用橡胶的光谱研究[J]. 光谱学与光谱分析, 1999, 19(4): 553-555
作者姓名:罗传秋  刘泳  杨继萍  翁健
作者单位:北京大学化学与分子工程学院,100871,北京
基金项目:分子动态与稳态结构国家重点实验室资助
摘    要:本文用衰减全反射傅里叶红外光谱和X射线光电子能谱对两种表面改性的耐药性能优良的医用橡胶样品进行了研究,结果表明两种样品表面层和体相组成完全不同,其表面层为氟化聚合物,体相为丁基橡胶。样品Ⅱ表面层氟的相对含量高于样品Ⅰ表面,县以CF2为主;在相同条件下进行氩离子刻蚀,样品Ⅱ表面层样品Ⅰ表面层不同深度的F/C原子比的变化相对小。

关 键 词:医用橡胶  表面改性  红外光谱  光电子能谱

The Spectral Study of the Surface Modified Medical Rubber
Chuanqiu LUO,Yong LIU,Jiping YANG,Jian WENG. The Spectral Study of the Surface Modified Medical Rubber[J]. Spectroscopy and Spectral Analysis, 1999, 19(4): 553-555
Authors:Chuanqiu LUO  Yong LIU  Jiping YANG  Jian WENG
Affiliation:Institute of Polymer Science, College of Chemistry, Peking University, 10087 Beijing.
Abstract:In this article ,the drug-resistance of two kinds of medical rubber whose surfaces have been modified were investigated by ATR-FTIR and XPS. The experimental results show that the compositions of the two samples'surface and body are different. The surface is fluorinated rubber although the body is butyl rubber. The ratio of fluorine to carbon atom in sample Ii -1 is higher than that in sample I -1. The principal join between F and C is the form--CF2--in sample II -1,but in sample I -1 it is the form--CF2-- and--CHF--. The change for F/C of the different depth in sample II- 1 was relatively less than that in sample I -1 when they were etched by argon ion bundle in the same conditions.
Keywords:Medical rubber   Surface modification   ATR FTIR   XPS  
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