Synthesis of poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate]: Thermal and optical properties of the copolymers with methyl methacrylate |
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| Authors: | Dingying Zhou Yoshiyuki Okamoto |
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| Institution: | a Polymer Research Institute, Polytechnic University, 6 Metrotech Center, Brooklyn, NY 11201, USA
b Faculty of Science and Technology, Keio University, Yokohama 223-8522, Japan |
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| Abstract: | Poly1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate (I)] was synthesized, and the copolymers of the monomer I with various compositions of methyl methacrylate (MMA) were prepared and characterized. The glass transition temperature values obtained for the copolymers were between 120 and 150 °C. The refractive indices of the copolymers were in the range of 1.4350-1.4872 at 532 nm. They were thermally stable (up to 297-323 °C), and their water absorptive properties were greatly decreased, compared with pure PMMA. |
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| Keywords: | Co polymerization Fluorinated methacrylate Water absorption Thermal property Optical property Dipole-dipole interaction |
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