N-Polyfluoro(trimethylsilyl)ethyl azole derivatives |
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| Authors: | Kirill I Petko Sergey Y Kot Lev M Yagupolskii |
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| Institution: | Institute of Organic Chemistry, National Academy of Science of Ukraine, Murman'ska, str. 5, 02094 Kyiv, Ukraine |
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| Abstract: | A facile synthetic route to N-polyfluoro(trimethylsilyl)ethyl azole derivatives was developed starting from N-bromo(chloro)polyfluoroethyl-substituted azoles. The silanes thus obtained were reacted with various electrophiles in the presence of the fluoride ion to yield the corresponding fluorinated carbinols, ketones, carboxylic acids, and methyl dithiocarboxylates as well as N-pentafluoroethylbenzimidazole. |
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| Keywords: | N-Polyfluoro(trimethylsilyl)ethylazoles C-nucleophiles N-Pentafluoroethylbenzimidazole |
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