Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions |
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| Authors: | Clark J Stephen Roche Caroline |
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| Institution: | School of Chemistry, University of Nottingham, University Park, Nottingham, UKNG7 2RD. j.s.clark@nottingham.ac.uk |
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| Abstract: | Asymmetric allylic amination or oxidation can be achieved by reaction of an alkene with a peroxycarbamate catalysed by a chiral copper bis-oxazoline complex, and the reaction can be tuned to give either the amination or oxidation product by reagent choice. |
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