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Effect of micelles on the acid hydrolysis of N-phenylbenzohydroxamic acid
Authors:Kallol K. Ghosh and Santosh K. Sar
Affiliation:(1) School of studies in Chemistry, Pt, Kavishankar Shuka University, 492 010 Raipur, M.P., India;(2) Bhilai Institute of Technology, Bhilai, India
Abstract:The effect of cationic (cetylpyridinium bromide and cetylpyridinium chloride) anionic (sodium dodecyl sulfate and lithium dodecyl sulfate) and non-ionic (Brij-35 and Triton-X-100) micelles on the acid-catalyzed hydrolysis of N-phenylbenzohydroxamic acid in 20 vol.% dioxane medium has been investigated. The kinetic results are explained by both pseudo-phase and Piszkiewicz cooperativity models.
Keywords:Micellar catalysis  N-phenylbenzohydroxamic acid  acid hydrolysis  surfactants
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