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In situ ESR–UV/VIS/NIR spectroelectrochemistry of an empty fullerene anion and cation: The C82:3 isomer |
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| Authors: | Michal Zalibera Peter Rapta Lothar Dunsch |
| Institution: | aGroup of Electrochemistry and Conducting Polymers, Leibniz-Institute for Solid State and Materials Research (IFW) Dresden, D-01171 Dresden, Germany;bDepartment of Physical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinskeho 9, SK-81237 Bratislava, Slovak Republic |
| Abstract: | The application of in situ ESR–UV/VIS/NIR spectroelectrochemistry to the highly purified C82:3 fullerene isomer with C2 symmetry made the detailed characterization of the radical structures formed by electrochemical generation possible. This first comprehensive spectroelectrochemical study of the stable radical anion and cation of an empty cage higher fullerene in acid-free organic electrolyte is a contribution to the general understanding of charged states at endohedral fullerenes. |
| Keywords: | Fullerenes Fullerene ions Ion radicals ESR– UV/VIS/NIR spectroelectrochemistry |
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