Lead bipyridyl hexacyanoferrate complex |
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| Authors: | M N Zhidkova A B Ilyukhin V Yu Kotov I A Stenina P -H Lin M Murugesu |
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| Institution: | 1.Moscow City Pedagogical University,Moscow,Russia;2.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia;3.Chemistry Department,University of Ottawa,Ottawa,Canada |
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| Abstract: | A low-solubility complex PbBipy2]6Fe(CN)6]4 · Bipy · 14H2O was prepared and characterized by physicochemical methods. Although containing PbBipy2]2Fe(CN)6] discrete species and a {PbBipy2]Fe(CN)6]}
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infinite chain in the crystal structure, the complex has weak antiferromagnetic properties over a wide temperature range.
The irreversible thermal destruction of the complex, which starts at 192°C, is preceded by complete dehydration. |
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