| Synthesis and Crystal Structure of Calix[4]arene Bearing a 1,8-Bis（propoxy）anthracene-9,10-dione |
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| 作者姓名： | GU Shao-Jin QIN Da-Bin JIN Lin-Hai |
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| 作者单位： | College of Chemistry and Chemical Engineering，China West Normal University |
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| 基金项目： | 华西师范大学科学研究基金，Youth Fund Projects of Sichuan Educational Department |
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| 摘 要： | The title complex （C50H44C14O8） was synthesized and structurally determined by single-crystal X-ray diffraction method. It crystallizes in monoclinic, space group P21/n with a = 19.7768（4）, b =10.2085（2）, c = 21.2721（4）A,β= 97.153（1）°, V = 4261.23（14）A^3, Z = 4, Mr = 914.65, F（000） = 1904, Dc = 1.426 g/cm^3,μ = 0.336, the final R = 0.0550 and wR = 0.1647. The compound was structurally characterized by IR and ^1H NMR. The molecules are stacked through C-H...π interactions and intermolecular C-H...O hydrogen bonds.
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| 关 键 词： | Calix 芳烃派生物 合成 晶体结构 实验工具和试剂 |
Synthesis and Crystal Structure of Calix[4]arene Bearing a 1,8-Bis(propoxy)anthracene-9,10-dione |
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| GU Shao-Jin QIN Da-Bin JIN Lin-Hai.Synthesis and Crystal Structure of Calix[4]arene Bearing a 1,8-Bis(propoxy)anthracene-9,10-dione[J].Chinese Journal of Structural Chemistry,2008,27(9):1035-1038. |
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| Authors: | GU Shao-Jin QIN Da-Bin JIN Lin-Hai |
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| Institution: | College of Chemistry and Chemical Engineering, China West Normal University, Sichuan 637002, China |
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| Abstract: | The title complex (C50 H44Cl4O8) was synthesized and structurally determined by single-crystal X-ray diffraction method.It crystallizes in monoclinic, space group P21/n with a = 19.7768(4), b =10.2085(2), c = 21.2721(4) A, β = 97.153(1)°, V = 4261.23(14) A3, Z = 4, Mr = 914.65, F(000) = 1904, Dc = 1.426 g/cm3, μ = 0.336, the final R = 0.0550 and wR = 0.1647.The compound was structurally characterized by IR and 1H NMR.The molecules are stacked through C-H…π interactions and intermolecular C-H…O hydrogen bonds. |
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| Keywords: | calix[4]arene derivative synthesis crystal structure |
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