Copper Phthalocyanine‐Functionalized Graphitic Carbon Nitride: A Hybrid Heterostructure toward Photoelectrochemical and Photocatalytic Degradation Applications |
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| Authors: | Zhong‐Guo Liu Jia‐Yun Wan Ze Yang Prof Shi‐Quan Wang Dr Hang‐Xing Wang |
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| Institution: | Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, P.R. China |
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| Abstract: | In this work, alcian blue 8GX (AB), a copper(II) phthalocyanine derivative, was employed to functionalize graphitic carbon nitride (g‐C3N4) for the preparation of a highly efficient photocatalyst. The approach relies on a facile AB‐assisted ethanol/water mixed‐solvent exfoliation of bulk g‐C3N4. The as‐prepared g‐C3N4/AB hybrid possesses significantly enhanced solution dispersibility and photoelectrochemical performance resulting from the synergistic effect between g‐C3N4 and AB, which involves the optimization of intimate interfacial contact, extension of light absorption range, and enhancement of charge‐transfer efficiency. This synergy contributes enormously to the photocatalytic degradation of rhodamine 6G (R6G) under light irradiation. |
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| Keywords: | copper phthalocyanine functionalization graphitic carbon nitride mixed-solvent strategy photocatalytic activity |
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