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Molecular Orbital Controlling Donor Moiety for High‐Efficiency Thermally Activated Delayed Fluorescent Emitters
Authors:Jeong‐A Seo  Prof. Myoung‐Seon Gong  Wook Song  Prof. Jun Yeob Lee
Affiliation:1. Department of Chemical Engineering, SungKyunkwan University, Suwon, Gyeonggi, Republic of Korea;2. Department of Nanobiomedical Science and, BK21 PLUS NBM Global Research Center for Regenerative Medicine, Dankook University, Chungnam, Republic of Korea
Abstract:A new donor moiety, 7,7,13,13‐tetramethyl‐7,13‐dihydro‐5H‐indeno[1,2‐b]acridine (IAc), was developed to control the highest occupied molecular orbital (HOMO) dispersion of thermally activated delayed fluorescent (TADF) emitters. The IAc unit expanded the HOMO dispersion of the emitters and increased the quantum efficiency of the TADF devices up to 20.9 %.
Keywords:acridine  donor–  acceptor systems  high quantum efficiency  photoluminescence  photophysics  TADF
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