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Ion‐Free and Ion‐Pairing Assemblies of Anion‐Responsive π‐Electronic Systems Possessing Directly Linked Alkyl Chains
Authors:Dr. Yohei Haketa  Daisuke Katayama  Shinya Fukunaga  Dr. Yuya Bando  Dr. Tsuneaki Sakurai  Dr. Wakana Matsuda  Prof. Shu Seki  Prof. Hiromitsu Maeda
Affiliation:1. Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu, Japan;2. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto, Japan
Abstract:Alkyl‐substituted pyrrole‐based anion‐responsive π‐electronic systems formed supramolecular gels and liquid crystals through effective π–π stacking and van der Waals interactions. The addition of chloride as a planar cation salt afforded ion‐pairing assemblies as soft materials comprising planar receptor‐Cl? complexes and the cation.
Keywords:anion binding  assembled structures  ion pairs  pyrrole derivatives  π  -electronic molecules
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