Nanoscale spherical architectures fabricated by metal coordination of multiple dipyrrin moieties |
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Authors: | Maeda Hiromitsu Hasegawa Masahiro Hashimoto Takashi Kakimoto Takuya Nishio Satoru Nakanishi Takashi |
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Affiliation: | Department of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Kusatsu 525-8577, Japan. maedahir@se.ritsumei.ac.jp |
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Abstract: | Phenylethynyl-bridged dipyrrin "dimers" have performed ZnII complexation to give coordination polymers, which provided the fluorescent colloidal spherical objects in solution as well as on the substrate according to the spacer units. Using a mixture of THF and water, unique morphologies, such as bell-shaped and "golf ball"-like architectures, were observed. |
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