Phosphorylation of Pyrimidinophane in the Reversed Micellar Solutions of Cationic and Nonionogenic Surfactants |
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| Authors: | E P Zhil'tsova L A Kudryavtseva G A Gainanova A P Timosheva A S Mikhailov R H Giniyatullin A A Nafikova V S Reznik A I Konovalov |
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| Institution: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia |
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| Abstract: | Reactions of a macrocycle containing three pyrimidine fragments and N,N′-bis(2-methylthio-6-methylpyrimidin-4-yl)-hexamethylenediamine with p-nitrophenyl bis(chloromethyl)phosphinate in the micellar solutions of cetyltrimethylammonium bromide, polyethyleneglycol-600 laurate and their mixture in chloroform was investigated spectrophotometrically. Catalytic activity of micelles depends on their structure, concentration of surfactants, molar fraction of the latter in solution, and structure of the nucleophilic reagent. |
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