Formation of dihydroperoxide derivatives during the oxidation of cyclohexene and tetralin by dioxygen |
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| Authors: | Gy?rgy Dombi Ferenc Evanics Károly Jáky László J. Csányi |
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| Affiliation: | (1) Institute of Pharmaceutical Chemistry, A. Szent-Gy?rgyi Medical University, Szeged, Hungary;(2) Institute of Inorganic and Analytical Chemistry, A. József University, P.O. Box 44, 6701 Szeged, Hungary |
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| Abstract: | 1H- and13C-NMR investigations revealed that prolonged oxidation of unsubstituted cyclohexene and tetralin, containing symmetrical and weak allylic and benzylic CH bonds, results in the formation of both mono- and dihydroperoxo derivatives. |
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| Keywords: | Liquid-phase oxidation 1H- and13C-NMR detection of mono- and dihydro-peroxide formation |
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