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A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets
Authors:Costa José Sánchez  Barrios Leoní A  Craig Gavin A  Teat Simon J  Luis Fernando  Roubeau Olivier  Evangelisti Marco  Camón Agustín  Aromí Guillem
Institution:Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain.
Abstract:An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular cluster pair.
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