| 3-叔丁氧甲酰基氨基吡咯烷催化酮和硝基芳基乙烯的不对称Michael加成 |
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| 引用本文： | 李坤,李建国,袁伟成,张晓梅. 3-叔丁氧甲酰基氨基吡咯烷催化酮和硝基芳基乙烯的不对称Michael加成[J]. 合成化学, 2009, 17(2) |
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| 作者姓名： | 李坤 李建国 袁伟成 张晓梅 |
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| 作者单位： | 中国科学院,成都有机化学研究所,四川,成都,610041;中国科学院,研究生院,北京,10039;中国科学院,成都有机化学研究所,四川,成都,610041;河南师范大学,化学与环境科学学院,河南,新乡,453002;中国科学院,成都有机化学研究所,四川,成都,610041 |
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| 摘 要： | 用3-叔丁氧甲酰基氨基吡咯烷催化酮和硝基芳基乙烯的不对称Michael加成,并考察了反应物结构对加成的影响,得到了较高的收率和较好非对映选择性.
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| 关 键 词： | 吡咯烷 硝基芳基乙烯 酮 不对称Michael加成 |
Micheal Addition of Ketones to Nitro-aryl-ethene Catalyzed by 3-Butoxycarbonylamido-pyrrolidine |
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| LI Kun,LI Jian-guo,YUN Wei-cheng,ZHANG Xiao-mei. Micheal Addition of Ketones to Nitro-aryl-ethene Catalyzed by 3-Butoxycarbonylamido-pyrrolidine[J]. Chinese Journal of Synthetic Chemistry, 2009, 17(2) |
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| Authors: | LI Kun LI Jian-guo YUN Wei-cheng ZHANG Xiao-mei |
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| Affiliation: | 1.Chengdu Institute of Organic Chemistry;Chinese Academy of Sciences;Chengdu 610041;China;2.Graduate University of Chinese Academy of Sciences;Beijing 100049;3.Department of Chemistry;Henan Normal University;Xinxiang 453002;China |
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| Abstract: | Asymmetric Micheal addition reaction of cyclohexanone and pentan-3-one to nitro-aryl-ethenes was studied using 3-butoxycarbonylamido-pyrrolidine as a catalyst.The influence of reactant structure on the addition reaction was investigated.The addition poducts were obtained in high yields and diastereoselectivities. |
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| Keywords: | pyrrolidine ketone nitro-aryl-ethene asymmetric Micheal addition |
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