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Synthesis of (24R)-homobrassinolide |
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| Authors: | V. A. Khripach V. N. Zhabinskii V. K. Ol'khovik |
| Abstract: | The synthesis from stigmasterol of C-29 brassinosteroids containing an (R)-ethyl group at C24 — (24R)-homocastasterone and (24R)-homobrassinolide — is described. The structure of the carbon skeleton of the side-chain was achieved by condensing a C-22 aldehyde with the appropriate sulfone |
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