Derivation of the dielectric loss formula (a theory of dielectric relaxation in glassy systems)

The derivation is given of the empirical formula tan $\text{σ = A(ω)[}\text{1}\text{B}\text{(T?T}{}_{\mathrm{c}}\text{)]}{}^2\text{sech}{}^2\text{[}\text{1}\text{B}\text{(T?T}{}_{\mathrm{c}}\text{)]}$, where A (ω), B and T_c are constants of the dipolar material at constant applied frequency ω, which has been shown to be in excellent agreement with experimental dielectric loss data on polymers and other amorphous glasses. The derivation is based on the dynamics of a two-level model. The energy splitting, Δ, of the system is derived and determined experimentally for polymers.