Ternary hydrogen halide/base/benzene mixtures: A new generation of liquid clathrates |
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| Authors: | Michele V. Gaudet Devin C. Peterson Michael J. Zaworotko |
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| Affiliation: | (1) Department of Chemistry, Saint Mary's University, B3H 3C3 Halifax, Nova Scotia, Canada |
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| Abstract: | Liquid clathrates have been prepared via contact of excess hydrogen halide (chloride or bromide) with benzene solutions of various simple organic nitrogen containing bases. The liquid clathrates or solutions so formed have been characterized via1H NMR and shown to be, as expected, ternary mixtures of hydrogen halide, benzene and salt. |
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| Keywords: | liquid clathrate room temperature melts NMR |
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