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Cu-catalyzed cross-couplings under ligandless conditions
引用本文:Chuan Zhou Tao Juan Li Xin Cui Yao Fu Qing Xiang Guo. Cu-catalyzed cross-couplings under ligandless conditions[J]. 中国化学快报, 2007, 18(10): 1199-1202. DOI: 10.1016/j.cclet.2007.07.016
作者姓名:Chuan Zhou Tao Juan Li Xin Cui Yao Fu Qing Xiang Guo
作者单位:Chuan Zhou Tao Juan Li Xin Cui Yao Fu Qing Xiang Guo~* Department of Chemistry,University of Science and Technology of China,Hefei 230026,China
摘    要:The possibility to carry out Cu-catalyzed cross-couplings under ligandless conditions was studied.It was found that by using K_3PO_4 as the base,the cross-coupling could proceed successfully between aryl iodides and several types of nucleophiles.Aryl bromides were completely inactive under the same reaction conditions.

关 键 词:杂交-耦合作用 铜元素 催化作用 配位体
收稿时间:2007-04-09
修稿时间:2007-04-09

Cu-catalyzed cross-couplings under ligandless conditions
Chuan Zhou Tao,Juan Li,Xin Cui,Yao Fu,Qing Xiang Guo. Cu-catalyzed cross-couplings under ligandless conditions[J]. Chinese Chemical Letters, 2007, 18(10): 1199-1202. DOI: 10.1016/j.cclet.2007.07.016
Authors:Chuan Zhou Tao  Juan Li  Xin Cui  Yao Fu  Qing Xiang Guo
Affiliation:Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
Abstract:The possibility to carry out Cu-catalyzed cross-couplings under ligandless conditions was studied.It was found that by using K_3PO_4 as the base,the cross-coupling could proceed successfully between aryl iodides and several types of nucleophiles.Aryl bromides were completely inactive under the same reaction conditions.
Keywords:Cu  Catalysis  Cross-coupling  Ligand free
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