| The synthesis and spectroscopic investigation of vinylated meso-tetraphen ylporphyrin |
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| 作者姓名： | Jin Qiang Xue Ya Qing Feng Lei Wang Ling Hui Wu |
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| 作者单位： | Jin Qiang Xue Ya Qing Feng Lei Wang Ling Hui Wu School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China |
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| 摘 要： | A series of new vinylated 5,10,15,20-tetraphenylporphyrins have been synthesized and characterized by ~1H NMR,MS,UV-vis and fluorescence studies.Following selective excitation of the porphyfin compounds with UV light,the energy is transferred to the porphyrin core and reemitted as red light.In comparison to tetraphenylporphyrin (TPP),the luminescence properties are markedly improved.
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| 关 键 词： | 卟啉 光谱 乙烯基 发光 |
| 收稿时间： | 4 June 2007 |
| 修稿时间： | 2007-06-04 |
The synthesis and spectroscopic investigation of vinylated meso-tetraphenylporphyrin |
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| Jin Qiang Xue Ya Qing Feng Lei Wang Ling Hui Wu.The synthesis and spectroscopic investigation of vinylated meso-tetraphen ylporphyrin[J].Chinese Chemical Letters,2007,18(11):1319-1322. |
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| Authors: | Jin Qiang Xue Ya Qing Feng Lei Wang Ling Hui Wu |
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| Institution: | School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China |
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| Abstract: | A series of new vinylated 5,10,15,20-tetraphenylporphyrins have been synthesized and characterized by ~1H NMR,MS,UV-vis and fluorescence studies.Following selective excitation of the porphyfin compounds with UV light,the energy is transferred to the porphyrin core and reemitted as red light.In comparison to tetraphenylporphyrin (TPP),the luminescence properties are markedly improved. |
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| Keywords: | Porphyrin Spectrum Vinylated Luminescence |
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