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Influence of PEG-borate ester on thermal property and ionic conductivity of the polymer electrolyte |
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| Authors: | Kato Y Hasumi K Yokoyama S Yabe T Ikuta H Uchimoto Y Wakihara M |
| Institution: | (1) Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552, Japan;(2) Alkylene Oxide Group 2, Oleochemicals Research Lab., NOF corporation, 3-3 Chidori-cho, Kawasaki-ku, Kawasaki, Kanagawa 210-0865, Japan |
| Abstract: | We have focused on the poly(ethylene glycol) (PEG)-borate ester as a new type plasticizer for solid polymer electrolyte for lithium ion secondary battery. Adding the PEG-borate ester into the electrolyte shows the increase in the ionic conductivity of the polymer electrolyte. By measuring the glass-transition temperature of the polymer electrolytes with DSC, it is found that the increase in ionic conductivity of the polymer electrolyte is due to the increase in ionic mobility. By investigating the temperature dependence of the ionic conductivity of the polymer electrolytes using William-Landel-Ferry type equation, we considered that the PEG-borate ester does not have any influence for dissociation of Li-salt. This revised version was published online in August 2006 with corrections to the Cover Date. |
| Keywords: | ionic conductivity polymer electrolyte WLF plot glass-transition temperature PEG-borate ester |
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