| 环糊精诱导室温燐光法中两种新型简便快速的除氧方法 |
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| 引用本文： | 张海容,魏雁声,晋卫军,刘长松.环糊精诱导室温燐光法中两种新型简便快速的除氧方法[J].分析化学,1996(11). |
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| 作者姓名： | 张海容 魏雁声 晋卫军 刘长松 |
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| 作者单位： | 山西大学化学系!太原，030006，山西省忻州师专化学系，山西大学化学系!太原，030006，山西大学化学系!太原，030006，山西大学化学系!太原，030006 |
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| 摘 要： | 在环糊精诱导室温燐光法中（CD－RTP）除氧技术是重要的实验条件。本文首次成功地建立了在反应体系中以Zn（s）＋HCl产生H2和Na2CO3＋HCl产生CO2作除氧剂，α－氯代萘作模型化合物的CD－RTP法。与传统的通氮除氧以及Na2SO3化学除氧方法相比，具有操作简便、除氧速度快、不受酸度严格控制、信号稳定等优点。
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| 关 键 词： | 环糊精诱导室温燐光 除氧技术 氢 二氧化碳 α-氯代萘 |
Two New Facile Deoxygenation Techniques for Cyclodextrin Induced Room Temperature Phosphorescence |
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| Zhang Hairong, Wei Yansheng, Jin Weijun, Liu Changsong.Two New Facile Deoxygenation Techniques for Cyclodextrin Induced Room Temperature Phosphorescence[J].Chinese Journal of Analytical Chemistry,1996(11). |
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| Authors: | Zhang Hairong Wei Yansheng Jin Weijun Liu Changsong |
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| Abstract: | The deoxygenation is one of the essential requirements in cyclodextrin induced room temperature phosphorescence. This paper originally presents two deoxygenation methods in which oxygen is removed by hydrogen or carbon dioxide respectively produced by thereaction Zn (s ) + HCl or Na2CO3 + HCl in measuring media. With 1, 2-dibromoethane as anexternal heavy atom perturber and a-chloronaphthalene as a model compound, these two newmethods show obvious advantages such as simpler facilities, faster deoxygenation speed.wider acidity range and more stable RTP signals etc, as compared with conventional N2 (g)Purging and Na2SO3 chemical deoxygenation. |
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