Characterisation and reproduction of yellow pigments used in central Italy for decorating ceramics during Renaissance

This study presents the characterisation of prototypical yellow pigments used during the Renaissance period in Italy and the successful reproduction of homologous materials in accordance with the ancient recipes. Moreover, a large number of yellow decorative layers of Sicilian ceramic artefacts dated back from 13th to the 19th century have been selected and the main chemical, structural and minero-petrografic features have been studied by X-ray diffraction, optical microscopy and scanning electron microscopy-energy dispersive spectrometry. These results have been compared with literature data of some yellow decorations of Renaissance ceramics made in central Italy. Comparison has also been made with homologous materials that have been successfully reproduced in accordance with ancient recipes described by Cipriano Piccolpasso in the textbook: “I Tre Libri dell’Arte del Vasaio” using the same ingredients proposed by this artist. Such yellow materials reproduce the typical yellow colorants used by craftsmen of relevant sites for ceramic fabrication in central Italy, namely Città di Castello, Urbino and Castel Durante, during the 16th century.Comparative arguments have shown some intriguing differences that are indicators of both technological transfer processes between central and southern Italy as well as of some local implementations likely due to specific raw materials locally available. PACS 81.05.Je; 82.80.-d; 68.37.Hk; 68.55.-a; 61.66.Fn; 61.10.Nz