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Binary-surfactant (Brij 35 + Tween 20) assisted preparation of highly dispersed Pt nanoparticles on carbon
Authors:Dong-Ha Lim  Lianhai Lu  Dong Baek Kim  Dong-Hyeok Choi  Dal-Ryung Park  Ho-In Lee
Institution:(1) School of Chemical and Biological Engineering and Research Center for Energy Conversion and Storage, Seoul National University, Seoul, 151-744, Korea;(2) Center for Gas Utilization Technology, KOGAS R&D Center, Ansan, Kyunggi, 425-150, Korea
Abstract:Pt nanoparticles supported on Vulcan XC-72R, synthesized by a surfactant-stabilized colloidal method, exhibited excellent properties as anode catalyst for low-temperature fuel cell. The Pt/C catalyst prepared with binary-surfactant (Brij 35 + Tween 20) at 10 times CMC had an average particle size of 2.8 nm with quite a narrow distribution between 2 and 4 nm. Our preparation method resulted in complete reduction of Pt and full loading of Pt nanoparticles on the carbon. The home-made Pt/C catalyst showed higher EAS and better catalytic activity than a commercial Pt/C catalyst. The method used in this study provided an easy and reproducible procedure for the preparation of Pt nanoparticles supported on carbon.
Keywords:Binary-surfactant  Brij 35  Tween 20  Nano Pt/C  Colloidal method  Composite nanomaterials
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