The danger of inadvertent heterogeneous catalysis when studying solution kinetics |
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| Authors: | M Spiro and E F G Barbosa |
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| Institution: | (1) Department of Chemistry, Imperial College of Science and Technology, SW 2AY London, England |
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| Abstract: | Reactions in solution can be heterogeneously catalyzed not only by conductance or e. m. f. electrodes but also by precipitates formed during the titration of qliquots. Attempts to follow a Menschutkin reaction by Volhard titrations revealed serious errors caused by the catalysis of a side reaction by insoluble silver salts.
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