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Palladium catalyzed synthesis of mandelate derivatives from arylboronic acids and glyoxylate hemiacetals |
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| Authors: | Mariko Sugaya Tetsuya Yamamoto Hiraku Shinozaki |
| Institution: | 1. Department of Materials Science and Engineering, Graduate School of Engineering, Tokyo Denki University, 5 Senju Asahi-cho Adachi-ku, Tokyo 120-8551, Japan;2. Department of Applied Chemistry, School of Engineering, Tokyo Denki University, 5 Senju Asahi-cho Adachi-ku, Tokyo 120-8551, Japan |
| Abstract: | NHC-coordinated cyclometalated palladium(II) catalyzed addition of arylboronic acids to methyl 2-hydroxy-2-methoxyacetate gave corresponding various functionalized methyl mandelate derivatives in good yields. |
| Keywords: | Palladium catalysis 1 2-Addition Arylboronic acid Glyoxylate hemiacetal |
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