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Palladium catalyzed aroylation of NH-sulfoximines with aryl halides using chloroform as the CO precursor
Authors:Sheng-rong Guo  Pailla Santhosh Kumar  Yan-qin Yuan  Ming-hua Yang
Institution:Department of Chemistry, Lishui University, 323000 Lishui, PR China
Abstract:A palladium-catalyzed aroylation of NH-sulfoximines for the efficient synthesis of N-aroyl sulfoximines from aryl halides and chloroform has been developed. The mild reaction conditions (temperature, catalyst loading) and the use of a CO surrogate render this transformation a useful method for the synthesis of N-aroyl sulfoximines from available feedstock.
Keywords:Aroylation  Sulfoximines  Chloroform  CO precursor
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