Synthesis of multi-functional epoxides derived from limonene oxide and its application to the network polymers |
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| Authors: | Hisatoyo Morinaga Mayu Sakamoto |
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| Institution: | 1. Faculty of Education, Graduate Faculty of Interdisciplinary Research, University of Yamanashi, 4-4-37, Takeda, Kofu, Yamanashi 400-8510, Japan;2. Faculty of Education and Human Sciences, University of Yamanashi, 4-4-37, Takeda, Kofu, Yamanashi 400-8510, Japan |
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| Abstract: | Bio-based multi-functional epoxides (1) such as bis-, tri-, and tetra-epoxides were synthesized by ene-thiol reactions between limonene oxide and polyhydric thiols. A cross-linking reaction of 1 with branched polyethyleneimine (BPEI) afforded the corresponding network polymers 2 with relatively high thermal resistance in high yields. |
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| Keywords: | Bio-based polymers Epoxides Cross-linking reaction Limonene |
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