Unique self-assembled 2D metal-tetrazolate networks: crystal structure and magnetic properties of [M(pmtz)2](M = Co(II) and Fe(II); Hpmtz = 5-(pyrimidyl)tetrazole) |
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| Authors: | Rodríguez Antonio Kivekäs Raikko Colacio Enrique |
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| Institution: | Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, E-18071 Granada, Spain. ecolacio@ugr.es antonio5@ugr.es. |
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| Abstract: | The title compounds, which have been prepared from M(II) salts (M = Co and Fe) and 5-(pyrimidyl)tetrazole under hydrothermal conditions, are isomorphous and exhibit a 2D square-grid-like structure; the cobalt complex is a spin-canted antiferromagnet with Tc= 15 K. |
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