| 吲哚环衍生物在直链淀粉柱上的拆分 |
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| 引用本文： | 葛晋,张红丽,赵亮,师彦平. 吲哚环衍生物在直链淀粉柱上的拆分[J]. 分析测试技术与仪器, 2007, 13(1): 30-32 |
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| 作者姓名： | 葛晋 张红丽 赵亮 师彦平 |
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| 作者单位： | 中国科学院,兰州化学物理研究所甘肃省天然药物重点实验室,甘肃,兰州,730000;中国科学院,研究生院,北京,100039;中国科学院,兰州化学物理研究所甘肃省天然药物重点实验室,甘肃,兰州,730000 |
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| 摘 要： | 选用不同的醇改性剂,在自制的直链淀粉-三(3,5-二甲基苯基氨基甲酸酯)(ADMPC)手性固定相上,对2种吲哚环衍生物对映体进行了手性拆分研究,并考察了样品的保留时间和立体选择性.
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| 关 键 词： | 手性拆分 直链淀粉-三(3,5-二甲基苯基氨基甲酸酯) 吲哚环衍生物 |
| 文章编号： | 1006-3757（2007）01-0030-03 |
| 收稿时间： | 2006-11-30 |
| 修稿时间： | 2007-01-18 |
Separation of Indole Ring Enantiomers on Amylase-tris (3, 5-dimethylphenylcarbamate) Chiral Stationary Phase |
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| GE Jin,Zhang Hong-Li,Zhao Liang and Shi Yan-Ping. Separation of Indole Ring Enantiomers on Amylase-tris (3, 5-dimethylphenylcarbamate) Chiral Stationary Phase[J]. Analysis and Testing Technology and Instruments, 2007, 13(1): 30-32 |
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| Authors: | GE Jin Zhang Hong-Li Zhao Liang Shi Yan-Ping |
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| Affiliation: | 1. Key laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences, Lanzhou 730000, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China |
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| Abstract: | Two enatiomers of indole ring derivatives have been chiral separated on amylase-tris(3,5-dimethylphenylcarbamate) chiral stationary phase(CSP),using hexane as the mobile phase with various alcohols as modifiers.The influence of the mobile phase composition on the enantioselectivity was discussed.By comparing the results from amylase-tris(3,5-dimethylphenylcarbamate) chiral stationary phase and cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase,the separation abilities are different on the two stationaries. |
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| Keywords: | chiral sepatation ADMPC enatiomers of indole ring derivatives |
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