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Enantioselective radical allylation reactions using chiral lanthanide Lewis acids |
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| Authors: | Mukund P Sibi Shankar Manyem Rajesh Subramaniam |
| Institution: | Department of Chemistry, Department of Chemistry, North Dakota State University, Fargo, ND 58105-5516, USA |
| Abstract: | Radical additions to oxazolidinone acrylate followed by allyl trapping were studied with chiral Lewis acids derived from lanthanide salts. Chiral ligands were evaluated to establish the  -stereocenter. Ligands with a prolinol framework along with achiral additives proved to be effective. The observed trends are compared with those in the literature. |
| Keywords: | lanthanide triflates radical allylation additives |
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