| 七甲茚基稀土络合物和碱金属盐的化学反应 |
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| 引用本文： | 陈立班,筒井稔,D.E.BERGBREITER. 七甲茚基稀土络合物和碱金属盐的化学反应[J]. 有机化学, 1985, 5(3): 223-227 |
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| 作者姓名： | 陈立班 筒井稔 D.E.BERGBREITER |
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| 作者单位： | 中国科学院广州化学所，美国德克萨斯农工大学化学系，美国德克萨斯农工大学化学系 |
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| 摘 要： | 本文用核磁共振等方法研究了稀土络合物和碱金属盐中的七甲茚基的质子化或氘化反应、亲核取代反应及络合物中稀土离子的还原反应。七甲茚基络合物比相应的茂基或茚基化合物更易与盐进行上述反应。三氘代七甲茚基在氘化反应中显示了同位素效应。
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| 关 键 词： | 茚(P) 稀土金属络合物 化学反应 同位素效应 核磁共振谱。 |
THE CHEMICAL REACTIONS OF HEPTAMETHYLINDENYL LANTHANIDE COMPLEXES AND ALKALI METAL SALTS |
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| Chen Liban Guangzhou Institute of Chemistry,Academia SinicaMinoru Tsutsui,David E.Bergbreiter Chemistry Department,Texas A , M University,U.S.A.. THE CHEMICAL REACTIONS OF HEPTAMETHYLINDENYL LANTHANIDE COMPLEXES AND ALKALI METAL SALTS[J]. Chinese Journal of Organic Chemistry, 1985, 5(3): 223-227 |
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| Authors: | Chen Liban Guangzhou Institute of Chemistry Academia SinicaMinoru Tsutsui David E.Bergbreiter Chemistry Department Texas A & M University U.S.A. |
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| Abstract: | The protonation or deuteration,the nucleophilic substitution of the hepta-methylindenyl groups in their lanthanide complexes and alkali metal salts,as well as thereduction of the lanthanide cations in the complexes were studied by NMR and other me-thods.Heptamethylindenyl groups favored these reactions more than the cy(?)lopentadienyland the indenyl groups in their analogous compounds.Deuterated heptamethylindenylcomplexes showed isotope effects upon the deuteration reaction. |
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| Keywords: | indene(P) rare earth metal complex chemical reaction isotope effect nuclear magnetic resonance spectrometry. |
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