Dimerization of the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)*mu(3)-acetone] via mercurophilic interactions |
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| Authors: | King Julie B Haneline Mason R Tsunoda Mitsukimi Gabbaï François P |
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| Affiliation: | Department of Chemistry, Texas A&M University, College Station 77843, USA. |
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| Abstract: | In the crystalline state, the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)*mu(3)-acetone] forms cofacial dimers which are held by two mercurophilic interactions of 3.51 A. In this form, the complex displays an intense photoluminescence with a sharp emission centered at 480 nm. |
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