| A Convenient Method for Synthesis of Novel Cyclic Ethers （IR, 2R,3R, 5S, 7S, 9R, 12R）-3-（t-Butyldimethylsilyl）oxy-7-methoxymethyl- oxy-2, 10-dimethyl-12-oxatricyclo [7.2.1.0^5,12] dodecane |
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| 作者姓名： | JieYAN MinZHU |
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| 作者单位： | [1]CollegeofPharmaceuticalSciences,ZhejiangUniversityofTechnology,Hangzhou310032 [2]CollegeofBiologicalandEnvironmentalSciences.ZhejiangShurenUnlversity,Hangzhou310015 |
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| 摘 要： | Novel cyclic esters (1R, 2R, 3R, 5S, 7S, 9R, 12R)-3-(t-butyldimethylsilyl)oxy-7-methoxymethyloxy-2, 10-dimethyl-12-oxatricyclo 7.2.1.0^5,12] dodecane were prepared when their precursor 1 was treated with SOC12/pyridine. A plausible mechanism was hypothesized.
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| 关 键 词： | 醚 化学结构 （1R 2R 3R 5S 7S 9R 12R）-3-（t-丁基二甲基甲硅烷基）氢氧基-7-甲氧基甲基-氢氧基-2 10-二甲基-12-氧杂环[7.2.1.0^5 12]十二烷 合成方法 |
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