Intramolecular cyclotrimerization of triynes catalyzed by N-heterocyclic carbene-CoCl2/Zn or -FeCl3/Zn |
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Authors: | Saino Naoko Kogure Daisuke Okamoto Sentaro |
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Institution: | Department of Applied Chemistry, Kanagawa University, Kanagawa-ku, Yokohama, Japan. |
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Abstract: | reaction: see text] Triynes 1 could effectively be cyclotrimerized to annulated benzenes 2 by treatment with a catalytic amount of zinc powder, N-heterocyclic carbene, and CoCl(2) or FeCl(3). |
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