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Helical tubulate inclusion compounds of ferrocene and squalene
Authors:Alison T. Ung  Roger Bishop  Donald C. Craig  Ian G. Dance  A. David Rae  Marcia L. Scudder
Affiliation:(1) School of Chemistry, The University of New South Wales, 2033 Kensington, N.S.W., Australia
Abstract:The inclusion compounds of 2,8-dimethyltricyclo[5.3.1.13,9]dodecane-syn-2,syn-8-diol,3, with ferrocene and with squalene have been prepared. The crystal structures of these helical tubulate compounds: (3)3·(ferrocene)0.75 [P3121,a=b=13.7480(6),c=7.0312(5) Å,Z=1,R=0.038] and (3)3·(squalene)0.23 [P3121,a=b=13.677(1),c=7.0533(9) Å,Z=1,R=0.042] are described.Supplementary Data relating to this article are deposited with the British Library as supplementary publication No. SUP 82151 (16 pages).
Keywords:Hydrogen bonding  alicyclic diol  helical tubulate  crystal structure  ferrocene  squalene
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