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Effect of crosslink density on some properties of electron beam-irradiated styrene–butadiene rubber
Authors:Qingguo Wang  Fenlan Wang  Kuo Cheng
Institution:aKey Laboratory of Rubber-plastics of Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China;bSchool of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;cJiangsu Dasheng Heat Shrinkable Material Co., Ltd. Wujiang city 215214, China
Abstract:Crosslink densities of electron beam (EB)-irradiated styrene–butadiene rubber (SBR) samples were measured by using a novel magnetic resonance crosslink density spectrometer (MRCDS). With 1,1,1-trimethylolpropane triacrylate (TMPTA) loading increasing, the crosslink density of EB-irradiated SBR increases up to a certain level, and then decreases in the irradiation dose range 50–200 kGy. Tensile strength, elongation at break, thermal stability and pyrolysis products of the EB-irradiated SBR samples with different crosslink densities were also studied in this paper.
Keywords:SBR  Electron beam irradiation  Crosslink density  Mechanical property  Thermal stability
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