卤化富勒烯研究进展

自从C60被发现并能被大量制备以来,富勒烯化学已成为有机化学学科发展最快的领域之一。富勒烯通过多加成反应形成具有独特结构和性能的富勒烯卤化物和全氟烷基化物,为设计合成新型富勒烯基功能材料开辟了新方向。本文综述了近几年来在卤化富勒烯和全氟烷基化富勒烯的合成方法、结构及性能方面取得的最新进展,重点介绍了氟化富勒烯及其衍生化反应,并展望了该领域今后的发展趋势。

The Recent Progress in Halogenated Fullerenes

Since the discovery and large scale preparation of C_(60), the chemistry of fullerenes has become one of the most developing fields in organic chemistry.Halogenated and perfluoroalkylated fullerenes formed by multi-addition reaction of the fullerene spheroid possessed unique structures and properties,which pioneer one of the new directions for the design of new pattern promising materials based on fullerenes.This paper reviews the progress on the synthetic methods,structures and general properties of halogenated and perfluoroalkylated fullerenes in recent years.Fluorinated fullerene and their derivatives are especially described.The research trends for the future are proposed.