Crystal structure of potassium tetramethylammonium hexacyanocobaltate(III) trihydrate: K3(Me4N)3[Co(CN)6]2·3H2O |
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| Authors: | René Guardiola Romero Angel Dago Morales Julio Duque Rodríguez José Fernández Bertrán |
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| Institution: | 1. Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ciudad de la Habana, Cuba
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| Abstract: | The structure of K3(Me4N)3Co(CN)6]2·3H2O has been determined from three-dimensional X-ray diffraction data. The unit cell is formed by parallel layers of cobalt
octahedra CoC6] and potassium octahedra, K(1)N5O(1)], separated byc/2. In each layer both types of octahedra are located alternatively. The MeN4]+ tetrahedra are located in the cavities between the two layers of octahedra. The crystal structure of this compound is the
first example of its type.
TMC 2483 |
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