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Weak aggregation: State of the art,expectations and open questions
Institution:1. Institute for Separation Chemistry of Marcoule, F-30207 Bagnols-sur-Cèze, France;2. Institute of Physical and Theoretical Chemistry, University of Regensburg, D-93040 Regensburg, Germany;1. Institute of Physical and Theoretical Chemistry, University of Regensburg, 93040 Regensburg, Germany;2. Faculty of Chemistry and Technology, University of Split, Ru?era Bo?kovi?a 35, 21000 Split, Croatia;1. Laboratoire de Physique des Solides, CNRS UMR8502, Université Paris-Sud, Université Paris-Saclay, 91405 Orsay,France;2. Laboratoire de Génie Chimique, CNRS UMR 5503, Université de Toulouse, F-31030 Toulouse, France
Abstract:This paper gives an overview of weak aggregation due to long-range molecular forces beyond the first neighbor. Such subtle self-assemblies are an important part of modern colloidal chemistry and concern organic molecules as well as inorganic electrolytes and hybrid aggregates. Diverse aspects of such colloidal aggregations, as described in this special issue, can be characterized by the effective free energy per molecule involved. We discuss here expectations about emerging knowledge in this field and predictive modeling of inorganic as well as organic colloids and hybrid aggregates. Some still open questions are also given.
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