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Critical view on TL/OSL properties of Li2B4O7 nanoparticles doped with Cu,Ag and co-doping Cu,Ag: Dose response study
Affiliation:1. Department of Nanotechnology, North-Eastern Hill University, Shillong, Meghalaya 793022, India;2. Radiological Physics and Advisory Division, Bhabha Atomic Research Centre, Mumbai, Maharashtra, India;3. Ex-Radiological Physics and Advisory Division, Bhabha Atomic Research Centre, Mumbai, Maharashtra, India;4. Department of Physics, Manipur University, Canchipur, Manipur, India;5. Department of Biochemistry, North-Eastern Hill University, Shillong, Meghalaya 793022, India;1. Physics Department, Oklahoma State University, Stillwater, OK 74078, USA;2. Department of Radiation Oncology, The University of Oklahoma HSC, Oklahoma City, OK 73104, USA;3. Landauer, Inc., Stillwater Crystal Growth Division, Stillwater, OK 74074, USA;4. Department of Radiation Safety and Security, Paul Scherrer Institut (PSI), Villigen PSI, Switzerland;1. Çukurova University, Art Sciences Faculty, Physics Department, Balcalı, 01330 Sarıçam, Adana, Turkey;2. Adiyaman University, Engineering Faculty, Department of Electrical Electronic Engineering, 02040 Adiyaman, Turkey;3. Mersin University, Art Sciences Faculty, Physics Department Mersin Turkey;4. Çukurova University, Art Sciences Faculty, Chemistry Department, Balcalı, 01330 Sarıçam, Adana, Turkey;5. Inonu University, Engineering Faculty, Department of Mining Engineering, 44280 Malatya, Turkey;6. Çukurova University, Ceyhan Engineering Faculty, Department of Chemical Engineering, Adana, Turkey;7. Sidney Kimmel Medical College, Thomas Jefferson University, Philadelphia, PA, USA;8. Baskent University Hospital, Barracks Health Campus, Radiation Oncology Department, Adana, Turkey;1. Nuclear Science and Technology Research Institute, Karaj, Iran;2. Department of Physics, Faculty of Science, University Putra Malaysia, Selangor, Malaysia;3. Department of Materials Science & Engineering, National University of Singapore, Singapore, Singapore;4. Young Researchers and Elite Club, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran;5. Institute of Advanced Technology, University Putra Malaysia, Selangor, Malaysia;6. Health Physics Group, Malaysian Nuclear Agency, Bangi, Selangor, Malaysia;7. Center for Quantum Devices, Department of Electrical and Computer Engineering, North Western University, Evanston, IL, USA;1. Department of Engineering Physics, Air Force Institute of Technology, Wright-Patterson Air Force Base, OH 45433, USA;2. Institute of Physical Optics, 23 Dragomanov St., Lviv 79005, Ukraine;3. Department of Physics, West Virginia University, Morgantown, WV 26506, USA;1. Çukurova University, Art Sciences Faculty, Physics Department, 01330 Balcalı Sarıçam Adana, Turkey;2. Mersin University, Art Sciences Faculty, Physics Department Mersin, Turkey;3. Inonu University, Engineering Faculty, Department of Mining Engineering, 44280 Malatya, Turkey;4. Sidney Kimmel Medical College at Thomas Jefferson University, Philadelphia, PA, USA;5. Sheba Medical, Center Radiation Oncology Department, 52621 Tel HaShomer, Israel;6. Adiyaman University, Engineering Faculty, Department of Electrical Electronic Engineering, 02040 Adiyaman, Turkey
Abstract:Small size (25 nm) Li2B4O7 nanoparticles doped with different concentrations of Cu, Ag and co-doped with Cu, Ag were prepared by solid state sintering at 700 °C. The crystalline phase and particle sizes analysis were carried out by XRD and TEM. FTIR study reveals the formation of vibrational bonds at 1600–1200 cm−1, 1500–700 cm−1, 950–870 cm−1 and 870–415 cm−1. The kinetic parameters of the TL glow curves were evaluated using CGCD procedure in R-software. The CW-OSL decay curves were fitted with third order exponential decay curves and photoionization cross sections of each component were evaluated. The lifetime of the main TL dosimetric peak were also calculated to check the stability of the signal. Dose responses of the synthesized Li2B4O7 nanoparticles for both the TL and CW-OSL were studied in the range of 0.02 mGy to50 Gy and found to be linear upto this range. Fading of the CW-OSL decay curves were also studied. The MDD of the synthesized samples were also calculated and observed to be 15 μGy.
Keywords:Thermoluminescence (TL)  Optically stimulated luminescence (OSL)  Dose response
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