Sequential ruthenium-catalyzed hydroamination and rhenium-catalyzed C-H bond activation leading to indene derivatives |
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Authors: | Kuninobu Yoichiro Nishina Yuta Takai Kazuhiko |
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Institution: | Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Japan. kuninobu@cc.okayama-u.ac.jp |
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Abstract: | reaction: see text] Formal 3 + 2] annulation of arylacetylenes and alpha,beta-unsaturated carbonyl compounds is achieved in a one-pot reaction by successive treatment of the acetylenes with aniline and a catalytic amount of Ru(3)(CO)(12) and NH(4)PF(6) and C-H bond activation catalyzed by ReBr(CO)(3)(thf)](2). The result suggests that the second rhenium-catalyzed indene formation is not disturbed by the first catalyst system. |
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