Electrochemical behaviour ofcis-dichloro(arylisocyanide)(tertiaryphosphine) platinum (II) and palladium(II) complexes in an aprotic solvent |
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| Authors: | Piero Zanello Renato Seeber Arnaldo Cinquantini Bruno Crociani |
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| Institution: | (1) Istituto di Chimica Generale dell'Università, Piano dei Mantellini 44, 53100 Siena, Italy;(2) Centro Chimica Tecnologia Composti Metallorganici Elementi Transizione C.N.R. Istituto di Chimica Industriale, Via Marzolo 9, 35100 Padova, Italy |
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| Abstract: | Summary The electrochemical behaviour of neutral platinum(II) and palladium(II) isocyanide complexes has been investigated in an aprotic medium at platinum and mercury electrodes. Platinum(II) derivatives are reduced to platinum(0) species, Palladium(II) compounds give rise to palladium(0) species at room temperature, while at 0° it is possible to obtain palladium(I) compounds. |
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