COads spillover and low-temperature activity of heterophase catalysts in CO oxidation |
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Authors: | V I Savchenko |
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Institution: | (1) Federal Scientific Center, Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia |
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Abstract: | The kinetics of CO oxidation on heterophase surfaces composed of two different types of patches M1 and M2 is analyzed. The kinetic conjugation of the patches caused by COads spillover leads to the substantial change in reaction rate temperature dependences, as well as to the appearance of a low-temperature, superadditive activity. |
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